A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS     

Lin Xu  Chongguang Luo  Hanjie Wen 《Geostandards and Geoanalytical Research》2020,44(1):201-214

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   

两株南极枝孢霉属真菌Cladosporium sp.NJF4和NJF6的次级代谢产物研究          下载免费PDF全文

常俊男  田晓清  樊成奇  黄金昌  陆亚男  韩清华 《极地研究》2020,32(1):60-67

南极因其独特的自然环境成为潜在、重要的微生物资源库,是产生新型生物活性物质和先导化合物菌株的潜在种源地,南极微生物正在成为创新药物研究新的重要资源。虽然近年来对南极微生物次级代谢产物的研究逐渐增加,但与温带和热带微生物研究相比仍处于初级阶段。对从南极普里兹湾海洋沉积物中获得的两株枝孢霉属真菌Cladosporium sp. NJF4和NJF6进行次级代谢产物分离及结构鉴定,获得20个化合物。化合物结构类型包括甾醇(1)、倍半萜类(7—8)、生物碱类(9—14)、二酮哌嗪(2—5、15—17)、芳香酸(6、18—19)等,其中倍半萜类(7—8)为首次从枝孢霉属真菌中分离得到,以上研究将为丰富南极微生物次级代谢产物库奠定一定的研究基础。  相似文献   

Effects of the improper modeling of viscous damping on the first-mode and higher-mode dominated responses of base-isolated buildings     

Hamidreza Anajafi  Ricardo A. Medina  Erin Santini-Bell 《地震工程与结构动力学》2020,49(1):51-73

In many finite element platforms, a classical global damping matrix based on the elastic stiffness of the system (including isolators) is usually developed as part of the solution to the equations of motion of base-isolated buildings. The conducted analytical and numerical investigations illustrate that this approach can lead to the introduction of unintended damping to the first and higher vibration modes and the spurious suppression of the respective structural responses. A similar shortcoming might be observed even when a nonclassical damping model (ie, an assembly of the superstructure and isolation system damping sub-matrices) is used. For example, the use of Rayleigh damping approach to develop the superstructure damping sub-matrix can lead to the undesired addition of damping to the isolated mode arising from the mass-proportional component of the superstructure damping. On the other hand, the improper use of nonclassical stiffness-proportional damping (eg, determining the proportional damping coefficient, β_k , based on the first mode) can result in assigning significant damping to the higher-modes and the unintended mitigation of the higher-mode responses. Results show that a nonclassical stiffness-proportional model in which β_k is determined based on the second modal period of a base-isolated building can reasonably specify the intended damping to the higher modes without imparting undesirable damping to the first mode. The nonclassical stiffness-proportional damping can be introduced to the numerical model through explicit viscous damper elements attached between adjacent floors. In structural analysis software such as SAP2000®, the desired nonclassical damping can be also modeled through specifying damping solely to the superstructure material.  相似文献   

隔震曲线梁桥不同等级地震的振动特性模拟分析          下载免费PDF全文

高菁阳 《地震工程学报》2020,42(3):607-612

曲线桥梁抗震特性模拟分析对于曲线桥梁隔震、减震有着重要意义。基于隔震曲线桥梁设计过程中的特点,通过非线性水平弹簧单元对铅芯橡胶支座双向非线性的能力进行模拟,根据SAP2000科学选择强震观测地震波,并考量曲线桥梁本身存在的特性对桥梁振动特性产生的影响,针对隔震曲线桥梁在不同等级地震下振动特征进行模拟分析,其中,通过隔震曲线桥梁铅芯橡胶支座模型的构建和梁桥不同等级地震计算模型、输入地震波与传感器量测等步骤得到的模拟结果为:不同地震波与加速度峰值输入过程中,地震动较小下的支座水平刚度比较大,且结构相对稳定;地震幅值增大时,桥梁支座水平刚度减小,且支座的恢复力位移滞回变化曲线面积比较大,能够更多地将地震输入能量消散掉,减小能量不断向曲线桥梁上方传递的速度,可有效减轻地震反应,起到隔震的效果。  相似文献   

复杂地震激励下隔震结构地震响应研究进展   总被引：1，自引：1，他引：0       下载免费PDF全文

张克纯  李凝志 《地震工程学报》2020,42(5):1270-1275,1336

隔震技术作为当前最有效的结构减震控制技术之一，在世界各国高烈度地区广泛建造。随着隔震技术的大范围推广，建造工况更为复杂的隔震工程随之不断涌现。系统深入研究复杂地震激励下隔震结构地震响应，是隔震工程长期安全服役的重要保障，也是隔震技术能够不断完善和推广的坚实基础。本文从复杂地震激励涵盖的多维地震、近场和近断层地震、行波效应以及土与结构相互作用四个主要方面入手，依据国内外相关文献开展综述，探讨了复杂地震激励下隔震结构研究存在的问题，并对此进行展望。  相似文献   

利用惯容隔震系统的结构层间隔震研究          下载免费PDF全文

张瑞甫  吴明瑞  周方圆  吴应雄  江洁玲 《世界地震工程》2020,(4):008-16

层间隔震技术对于结构竖向不规则以及结构增层等状况有良好的适用性。然而，层间隔震可能出现的较大隔震层变形会带来结构设计的困难。通过在隔震层中设置阻尼元件可以减少变形，但是过大的阻尼出力和过多的数量需求可能导致空间布置和安装不便。惯容元件为解决以上问题提供了一种新的途径。该研究提出采用惯容隔震系统作为层间隔震提高能量耗散效率的手段以控制地震响应，同时也给出了基于性能需求的惯容层间隔震的参数优化设计方法。并以一个标准钢结构模型验证了方法的有效性。结果表明:惯容元件的使用显著降低了上部子结构的地震响应和隔震层的变形，惯容系统实现了预期的耗能增效作用。  相似文献   

Response of hybrid isolation system during a shake table experiment of a full‐scale isolated building     

Keri L. Ryan  Taichiro Okazaki  Camila B. Coria  Eiji Sato  Tomohiro Sasaki 《地震工程与结构动力学》2018,47(11):2214-2232

A full‐scale 5‐story steel moment frame building was subjected to a series of earthquake excitations using the E‐Defense shake table in August, 2011. For one of the test configurations, the building was seismically isolated by a hybrid system of lead‐rubber bearings and low friction roller bearings known as cross‐linear bearings, and was designed for a very rare 100 000‐year return period earthquake at a Central and Eastern US soil site. The building was subject to 15 trials including sinusoidal input, recorded motions and simulated earthquakes, 2D and 3D input, and a range of intensities including some beyond the design basis level. The experimental program was one of the first system‐level full‐scale validations of seismic isolation and the first known full‐scale experiment of a hybrid isolation system incorporating lead‐rubber and low friction bearings. Stable response of the hybrid isolation system was demonstrated at displacement demands up to 550 mm and shear strain in excess of 200%. Torsional amplifications were within the new factor stipulated by the code provisions. Axial force was observed to transfer from the lead‐rubber bearings to the cross‐linear bearings at large displacements, and the force transfer at large displacements exceeded that predicted by basic calculations. The force transfer occurred primarily because of the flexural rigidity of the base diaphragm and the larger vertical stiffness of the cross‐linear bearings relative to the lead‐rubber bearings.  相似文献   

新型钢弹簧浮置板道床隔振试验与数值分析研究          下载免费PDF全文

高扬  张强  刘文光  李腾 《世界地震工程》2020,(3):038-47

提出了一种附加位移放大杠杆的新型钢弹簧浮置板道床隔振装置并进行了理论分析，给出了该装置基于位移放大倍数的阻尼力和耗能计算公式。同时设计制作了附加3倍位移放大的新型钢弹簧浮置板道床隔振装置并进行了地铁振动测试，试验结果表明:该装置隔振效果显著。通过建立新型钢弹簧浮置板道床隔振系统有限元分析模型，数值模拟结果与实测振动数据可进行较好的吻合，结果表明:新型钢弹簧浮置板道床隔振系统能有效地减小结构的动力响应。  相似文献   

金川铜镍硫化物矿床中铂族矿物的主要类型和产出特征:热液蚀变过程中铂族元素的富集机理     

董宇  魏博  王焰 《岩石学报》2021,37(9):2875-2888

金川铜镍硫化物矿床是我国最主要的铂族元素(PGE)资源产地,其矿石受热液蚀变作用影响明显,并产出多种铂族矿物(PGM)。岩浆演化和热液蚀变过程中PGE的迁移富集机制和PGM的成因,一直是研究PGE地球化学行为非常关注的问题。本文对金川铜镍硫化物矿床中PGM的研究发现,其主要类型包括含PGE的硫砷化物(硫砷铱矿)和砷化物(砷铂矿),Pd的铋化物、碲化物和硒化物,以及少量其他铂族矿物。其中,硫砷铱矿可包裹于各种贱金属硫化物(镍黄铁矿、磁黄铁矿和黄铜矿)中,表明硫砷铱矿可能结晶于早期的含As硫化物熔体,随后被包裹于硫化物熔体冷凝分异产生的单硫化物固溶体(MSS)和中间硫化物固溶体(ISS)中。硫化物熔体中的As可能主要通过地壳混染作用加入幔源岩浆。大量铋钯矿(PdBi)呈微细乳滴状包裹于黄铜矿中,为晚期ISS冷凝形成黄铜矿过程中出溶的产物。少量铋钯矿(PdBi_2)呈不规则状充填于矿物裂隙,与次生磁铁矿脉紧密共生,并随矿石的蚀变程度增加,铋钯矿的化学成分由PdBi逐渐向PdBi_2转变,表明这部分铋钯矿为后期热液蚀变产物。铋碲钯矿和钯的硒化物则主要产出于镍黄铁矿裂隙且与次生磁铁矿紧密共生,指示明显的热液成因。钯的硒化物的出现表明,岩浆期后酸性、高盐度、高氧逸度的富Cl~-流体对金川铜镍硫化物矿床中Pd的迁移和富集起到了关键控制作用。  相似文献   

酉阳河流域典型年汛期的基流分割研究   总被引：2，自引：0，他引：2  

雷宇宽 《水文》2021,41(1):35-41

基流分割是水文学研究中的重难点问题之一,目前基流分割也存在许多方法。基于酉阳河典型年汛期实测日平均流量资料,分别采用Chapman-Maxwell改进方程数字滤波法一次滤波(参数N=1)以及二次滤波(参数N=2)、BFI(f)法、HYSEP固定步长法、HYSEP滑动步长法、HYSEP局部最小值法进行基流分割并对其结果进行分析对比。研究结果表明:不同方法下得到的基流分割线各不相同,各年份基流指数的统计特征也存在一定差异,采用Chapman-Maxwell改进方程数字滤波法二次滤波得到的基流成果更符合基流的一般特征以及酉阳河流域的降水径流关系特点。  相似文献